Low temperature Raman spectroscopic study has been performed on a Zcut LiNbO3 single crystal in the case of Z(xy)Z configuration. Low temperature studies were performed to be far from the critical temperature, which is known to be at 1165o C in Lithium Niobate, looking for possible anomalies or precursors of the phase transition. Room temperature Raman spectra revealed the presence of the E[TO] modes only, as predicted by the Raman selection rules and group theory for the Z(xy)Z configuration. Comparison of the Raman spectra at room temperature and lower temperatures shows a strong intensity attenuation and progressive reduction in the intensity of the Raman peaks, in addition to the appearance of the A1[TO] modes at 279, 336 and 629 cm-1, which are known to be forbidden modes of the Z(xy)Z configuration. A1[TO] modes resulted from the splitting of 581, 332 and 269 cm-1 vibrational modes into two branches below -100o C. Since the original 581 cm-1 band corresponds to a totally symmetric NbO6 stretching mode, this splitting was interpreted as due to a distortion in the NbO6 structure leading to two distinct sites for the NbO6 unit. This effect is explained as a result of inharmonic vibrations (quasisoft-mode) and the two-phonon state. The temperature dependence of the band parameters showed an inversion point at -100°C, and discontinuity near +150o C. These results indicate that a phase transition occurs at -100o C on cooling and near +150o C on heating, indicating that an abnormality in the structure of LiNbO3 is taking place.
(2008). Detection of Two Phases Coexisting at the Phase Transition Temperature in LiNbO3 single crystal by using Raman Spectroscopy. Egyptian Journal of Solids, 31(2), 175-184. doi: 10.21608/ejs.2008.148804
MLA
. "Detection of Two Phases Coexisting at the Phase Transition Temperature in LiNbO3 single crystal by using Raman Spectroscopy". Egyptian Journal of Solids, 31, 2, 2008, 175-184. doi: 10.21608/ejs.2008.148804
HARVARD
(2008). 'Detection of Two Phases Coexisting at the Phase Transition Temperature in LiNbO3 single crystal by using Raman Spectroscopy', Egyptian Journal of Solids, 31(2), pp. 175-184. doi: 10.21608/ejs.2008.148804
VANCOUVER
Detection of Two Phases Coexisting at the Phase Transition Temperature in LiNbO3 single crystal by using Raman Spectroscopy. Egyptian Journal of Solids, 2008; 31(2): 175-184. doi: 10.21608/ejs.2008.148804